![]() Rather, the random motion of the particles is superimposed by a directed movement of the cube. This is because it is no longer a random movement of the individual particles. Note that particle motion in the context of temperature is always a random motion! The temperature of the cube shown in the animation above would not increase if it were moved at high speed and the individual particles were supposed to be faster. More information on the connection between temperature and particle motion, especially for gases, can be found in the article “ Kinetic theory of gases“. The higher the temperature of a substance, the greater the kinetic energy of the particles! Animation: Influence of temperature on particle motion and thermal expansion Therefore the following statement applies : With a higher temperature and thus higher particle velocity, the kinetic energy of the particles also increases. The temperature of a substance can therefore be regarded as a measure of the velocity of the particles it contains. Animation: Influence of temperature on particle motion and thermal expansion Occupational Safety and Health Administration (OSHA) requires Material Safety and Data Sheets to give information about the volatility and flammability of liquids in order to help prevent accidents from occurring.If matter is heated and thus its temperature rises more and more, it can be seen that the particles contained in it move ever faster – be it the relatively free movement of the particles in gases or the oscillation around a rest position in solids. Any small spark, even one occurring from the friction between the gas particles themselves, can be enough to cause a catastrophic fire or even an explosion. This can be a fire hazard if the vapor is flammable. Substances with high vapor pressures can form a high concentration of gas particles above the liquid in a closed system. Increasing the temperature of the closed system will increase the vapor pressure, according to Purdue University's department of chemistry. The pressure exerted by the vapor/liquid equilibrium in the closed container is called the vapor pressure. ![]() ![]() When the rate of evaporation and the rate of condensation are the same, there will be no net decrease in the amount of liquid. Some of the evaporated particles will eventually come into contact with the remaining liquid and lose enough of their energy to condense back into the liquid. When a liquid evaporates inside a closed container, the particles cannot escape the system. Sublimation happens when a substance passes directly from solid to gas without passing through the liquid state. Volatility is more often a property of liquids, but some highly volatile solids may sublime at normal room temperature. Volatility can be thought of as how likely a substance will be to vaporize at normal temperatures. This phenomenon is known as evaporative cooling. As the faster particles escape, the remaining particles have lower average kinetic energy, and the temperature of the liquid cools. Evaporation occurs when surface particles gain enough kinetic energy to escape the system. When enough energy is transferred to a particle at the surface of the liquid, it will eventually overcome the surface tension holding it to the rest of the liquid. Such collisions transfer energy from one particle to another. Evaporationīecause the particles of a liquid are in constant motion, they will collide with one another, and with the sides of the container. When heated, the particles of the liquid move faster, allowing the liquid to flow more easily. Viscosity can usually be reduced by heating the liquid. ![]() Honey is thicker than water and flows more slowly. For example, honey is more viscous than water. A substance with low viscosity is considered to be thinner than a substance with higher viscosity, which is usually thought of as being thicker. A liquid that flows very slowly is said to be more viscous than a liquid that flows easily and quickly. Viscosity is a measure of how much a liquid resists flowing freely. One example of capillary action is when someone collects a sample of blood by touching a tiny glass tube to the blood droplet on the tip of a pricked finger. The most accurate measurement of the volume of a liquid in a graduated cylinder will be observed by looking at the volume marks closest to the bottom of this meniscus.Īdhesion also accounts for capillary action when a liquid is drawn up into a very narrow tube. The combination of cohesive and adhesive forces means that a slight concave curve, known as the meniscus, exists at the surface of most liquids. ![]()
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